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31.
The influence of the electron beam modification of a dual‐phase filler on the dynamic mechanical properties of styrene‐butadiene rubber (SBR) is investigated in the presence and absence of trimethylol propane triacrylate or triethoxysilylpropyltetrasulfide. Electron beam modification of the filler results in reduction of the tan δ at 70°C, a parameter for rolling resistance, and an increase in the tan δ at 0°C, a parameter for wet skid resistance of SBR vulcanizates. These modified fillers give significantly better overall performance in comparison with the control dual‐phase filler. This variation in properties is explained in terms of filler parameters such as the filler structure that leads to rubber occlusion and filler networking. These results are further corroborated using the master curves obtained by the time–temperature superposition principle. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2992–3004, 2003 相似文献
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The paper presents a theoretical analysis of stresses generated during convective drying of kaolin, based on elastic and viscoelastic models. The equations of these models were solved analytically for a cylindrically shaped sample; the distribution and evolution of the radial and circumferential stresses are illustrated in diagrams. The acoustic emission method was used in experimental tests for identification on line of the time period during which the stresses reach their maximal values. A better correlation has been found between the experimental tests and the theoretical predictions obtained on the basis of the viscoelastic model. 相似文献
34.
The relationship between the postcuring conditions and the fracture toughness of a bisphenol A‐type epoxy resin cured with acid anhydride was investigated. The glass transition temperature and fragility parameter, derived from the thermo‐viscoelasticity, were used to characterize the epoxy resin postcured under various conditions. Relationship between these two parameters and the fracture toughness was then investigated, based on the fractography results of a microscopic roughness examination of a fractured surface. The values of the glass transition temperature and fragility greatly depended on the postcuring conditions. The glass transition temperature was approximately 400 K when the crosslinking reaction was saturated. The fragility was independent of the saturation of the reaction and varied between 50 and 180. The results of the fracture test and fractography examination showed that there was no direct correlation between the glass transition temperature, the fracture toughness, and the roughness. On the other hand, there was a correlation between the fragility, fracture toughness, and roughness when the glass transition temperature saturated (at 400 K). As the fragility decreased from 180 to 50, the fracture toughness increased from 0.6 to 1.1 MPa · m1/2 at the same glass transition temperature. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 10: 2266–2271, 2002 相似文献
35.
Blending a crosslinked high‐density polyethylene (xHDPE) enhances melt strength and strain hardening behavior in elongational viscosity of high‐density polyethylene (HDPE) to a great degree. Gel fraction of xHDPE has a stronger effect on the strain hardening than sol fraction, although sol fraction also enhances the strain hardening to some degree. Further, the xHDPE crosslinked by peroxide in a compression mold exhibits more pronounced effect than xHDPE by radiation, which is attributed to the difference in the amount of the gel fraction. The xHDPE, which enhances the strain hardening, has sparse crosslink points in the network. Moreover, it was found from linear viscoelastic measurements, such as oscillatory modulus and relaxation modulus, that the xHDPE is characterized as a critical gel, which was also supported by the result of tensile testing. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 73–78, 2002 相似文献
36.
The effects of loading rate, fiber sizing, test temperature and global strain level on the adhesion strength between carbon fibers and a thermosetting epoxy (Epon 815) are studied using the single fiber fragmentation test procedure. Analytical methodology describing the viscoelastic behavior observed is also presented. The possibility of rate-temperature-interphase thickness superposition for the interfacial strength function is illustrated based on the analytical models discussed. Experimental data are discussed using Weibull statistics and also presented in the form of percent relative frequency histograms for the fiber fragments in a collective fashion. The use of histograms allows for interpretation of the skewness in the data population. 相似文献
37.
稀土顺丁橡胶与丁苯橡胶(SBR)共混,可以改善SBR的耐低温性能。当稀土顺丁橡胶/SBR(质量比)这20/80时,-30℃的tanδ仅小于SBR,60℃的tanδ最小。其共混胶的应力-应变性能、湿滑指数、磨耗及生热性能均优于镍系顺丁橡胶/SBR共混体系。 相似文献
38.
平台振动控制中粘弹性阻尼器及其位置优化 总被引:1,自引:1,他引:1
针对结构复杂的多自由度海洋平台模型,设计了粘弹性阻尼器,研究了基于粘弹性阻尼器的海洋平台振动控制及阻尼器的位置优化,考虑到粘弹性阻尼器的减振原理,采用层间相对位移的均方差作为阻尼器的定位准则,使海洋平台受控点的位移响应降低到允许的范围内。针对一个实际的7自由度的海洋平台计算模型,在随机波浪载荷作用下进行了平台振动响应分析及阻尼器的位置优化设计。结果表明,大跨安装阻尼器后平台位移响应谱幅度大大地降低。 相似文献
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通过2009年在黑龙江省杜蒙县一心乡进行的田间小区试验,研究了"大垄双行覆膜+膜下滴灌+垄向区田"和"行间覆膜+滴灌+垄向区田"两种技术集成措施在苗期、拔节期和灌浆期这三个生育期内灌不同量的水对玉米产量及其构成要素、水分利用效率等的影响,并分别提出了基于产量和水分利用效率的玉米不同生育阶段的最佳灌水量。 相似文献